Two guitars for most of this.
-- Guitar 1 --
It's just a D, barred (at 5). Sounds good on a Telecaster with the tone set all the way down.
E|-5-----------|
B|-7-7-7-7-7-7-|
G|-7-7-7-7-7-7-|
D|-7-7-7-7-7-7-|
A|-5-5-5-5-5-5-|
E|-------------|
[ Tab from: http://www.guitaretab.com/d/dappled-cities/190034.html ]
-- Guitar 2 --
A simple arpeggio, again with the D. Set the tone way up for it.
You can play it barre 5 too, it's a matter of preference.
E|---------2------------------------|
B|---3-------3--------3-------3-----|
G|-----2-------2--------2-------2---|
D|-0-----0-------0--------0-------0-|
A|----------------------------------|
E|----------------------------------|
The 2 on the high E is only played after the first time.